IJESD 2025 Vol.16(5): 332-337
doi: 10.18178/ijesd.2025.16.5.1541

Synergistic Photocatalytic Degradation and Hydrogen Production Performances of MWO4/tubular g-C3N4 Composites

Nurseli Görener Erdem1 , Özlem Tuna2 , Esra Bilgin Simsek1,*

  • 1Department of Chemical Engineering, Faculty of Engineering, Gebze Technical University, Kocaeli, Türkiye
  • 2Department of Chemical Engineering, Faculty of Engineering, Yalova University, Yalova, Türkiye

* Corresponding author

  • Manuscript receivedFebruary 26, 2025
  • revisedMarch 31, 2025
  • acceptedMay 14, 2025
  • publishedSeptember 18, 2025

Abstract

In this work, a series of heterojunction composites including MWO<sub>4</sub> (M: Ce, Cu, Co) and tubular-shaped graphitic carbon nitride were synthesized as efficient photocatalysts towards degradation of tetracycline antibiotic under visible light irradiation. The results showed that the hybridization of materials significantly an enhanced the photocatalytic decomposition activity in which removal rates were found as 90%, 88% and 89% for CuWO<sub>4</sub>/CN, CoWO<sub style="text-align: justify; text-wrap-mode: wrap;">4</sub>/CN and CeWO<sub style="text-align: justify; text-wrap-mode: wrap;">4</sub>/CN compared to that of pure CN (44%) after visible light irradiation for 2 h. Moreover, the photocatalytic hydrogen production rates were significantly enhanced after hybridization of the materials. The enhanced photocatalytic activity of MWO<sub>4</sub>/CN composites was attributed to the Z-scheme transfer mechanism, which reduced recombination through the identical interaction among the energy bands of materials. Both characterization and photocatalytic performance tests demonstrated that the MWO<sub>4</sub>/CN composites were successfully prepared with excellent activity and recyclability.

Keywords

  • carbon nitride
  • metal tungstate
  • transition
  • photocatalysis
  • antibiotic
IJESD-V16N5-1541

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Nurseli Görener Erdem, Özlem Tuna, and Esra Bilgin Simsek, "Synergistic Photocatalytic Degradation and Hydrogen Production Performances of MWO4/tubular g-C3N4 Composites," International Journal of Environmental Science and Development, vol. 16, no. 5, pp. 332-337, 2025. https://doi.org/10.18178/ijesd.2025.16.5.1541

Copyright & License

Copyright © 2025 by the authors. This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).

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